Engine Performance, Emission and Fluorescence study of fuel from Plant Oils
Author(s):
Nikul K Patel†*, Ragesh G Kapadia††, Romit Y Gandhi††† , Shailesh N Shah‡
Affiliation(s):
††Department of Mechanical Engineering, Shri S’ad Vidya Mandal Institute of Technology, Bharuch 392001, India
†††Department of Mechanical Engineering, Dharamsinh Desai Institute of Technology, Nadiad India
‡Department of Chemistry, Faculty of Science, The Maharaja Sayajirao University of Baroda, Vadodara 390001, India
ABSTRACT: Understanding of conventional fuel obtained from fossils extinct has prompted researcher to give way for fuel which is environmental friendly, renewable, non-toxic, biodegradable and easily usable. The fuel which can be extracted from straight vegetable oil using trans-esterification process and is proven to be prominent alternative fuel known as biodiesel. Fluorescence spectroscopic analysis was used to assess production of biodiesel from soybean refined vegetable oil. The results obtained by various author indicates that quality of biodiesel is affected by fluorescence spectra resulting into its effect on emissions and performance of an engine. This study further outlines about performance of engine and its emission using biofuel derived from oil like soybean, rapeseed, jatropha, neem and karanja which have been reread from various topical publications. The review enumerates that blend of biodiesel with conventional petro-diesel indicates promising results in terms of performance as well as emission control. Conclusively, biodiesel as an alternative fuel having huge potential around world in terms of economical production.
Keywords : Plant Oil, Biodiesel, Performance, Emission, Fluorescence.
[2] K. Bozbas, “Biodiesel as an alternative motor fuel: production and policies in the European Union”, Renewable and Sustainable Energy Reviews, vol. 12, no. 2, pp. 542-552, February 2008.
[3] J. Van Gerpen, “Biodiesel processing and production”, Fuel processing technology, vol. 86, no. 10, pp. 1097-1107, June 2005.
[4] L. C. Meher, D. V. Sagar, and S. N. Naik, “Technical aspects of biodiesel production by transesterification—a review”, Renewable and sustainable energy reviews, vol. 10, no. 3, pp. 248-268, June 2006.
[5] L. B. de Caland, E. L. Silveira, and M. Tubino, “Determination of sodium, potassium, calcium and magnesium cations in biodiesel by ion chromatography”, Analytica chimica acta, vol. 718, pp. 116-120, March 2012.
[6] M. de Souza Castilho, and N. R. Stradiotto, “Determination of potassium ions in biodiesel using a nickel (II) hexacyanoferrate-modified electrode”, Talanta, vol. 74, no. 5, pp. 1630-1634, February 2008.
[7] A. Datta, and B. K. Mandal, “Numerical investigation of the performance and emission parameters of a diesel engine fuelled with diesel-biodiesel-methanol blends”, Journal of Mechanical Science & Technology, vol. 30, no. 4, April 2016.
[8] A. K. Agarwal, “Biofuels (alcohols and biodiesel) applications as fuels for internal combustion engines”, Progress in energy and combustion science, vol. 33, no. 3, pp. 233-271, June 2007.
[9] A. Demirbas, “Progress and recent trends in biofuels”, Progress in energy and combustion science, vol. 33, no. 1, pp. 1-8, February 2007.
[10] J. Cvengroš, and F. Považanec, “Production and treatment of rapeseed oil methyl esters as alternative fuels for diesel engines”, Bioresource Technology, vol. 55, no. 2, pp. 145-50, February 1996.
[11] B. Zhan, C. Li, J. Yang, G. Jenkins, W. Huang, and X. Dong, “Graphene Field‐Effect Transistor and Its Application for Electronic Sensing”, Small, vol. 10, no. 20, pp. 4042-4065, October 2014.
[12] M. B. Lima, I. S. Barreto, S. I. Andrade, M. S. Neta, L. F. Almeida, and M. C. Araújo, “Photometric determination of phosphorus in mineralized biodiesel using a micro-flow-batch analyzer with solenoid micro-pumps”, Talanta, vol. 98, pp. 118-122, August 2012.
[13] Resolucao, “Agencia Nacional do Peroleo, Gas Natural e Biocombustives”, N 18, sexta-feira, January 2013.
[14] BSI BS EN 14214, “Automotive fuels – fatty acid methyl esters (FAME) for diesel engines – requirements and test methods”, BSI, 2008.
[15] ASTM D6751, “Standard specification for biodiesel fuel blend stock (B100) for middle distillate fuels”, West Conshohocken, PA: ASTM International, 2009.
[16] N. K. Patel, P. S. Nagar, and S. N. Shah, “Identification of non-edible seeds as potential feedstock for the production and application of bio-diesel”, Energy and power, vol. 3, no. 4, pp. 67-78, June 2013.
[17] Y. Zhang, M. A. Dube, D. D. McLean, and M. Kates, “Biodiesel production from waste cooking oil: 1. Process design and technological assessment”, Bioresource technology, vol. 89, no. 1, pp. 1-6, August 2003.
[18] S. Fernando, P. Karra, R. Hernandez, and S. K. Jha, “Effect of incompletely converted soybean oil on biodiesel quality”, Energy, vol. 32, no. 5, pp. 844-851, May 2007.
[19] B. E. Freedman, E. H. Pryde, and T. L. Mounts, “Variables affecting the yields of fatty esters from transesterified vegetable oils”, Journal of the American Oil Chemists’ Society, vol. 61, no. 10, pp. 1638-1643, October 1984.
[20] H. Noureddini, and D. Zhu, “Kinetics of transesterification of soybean oil”, Journal of the American Oil Chemists’ Society, vol. 74, no. 11, pp. 1457-1463, November 1997.
[21] M. Holčapek, P. Jandera, J. Fischer, and B. Prokeš, “Analytical monitoring of the production of biodiesel by high-performance liquid chromatography with various detection methods”, Journal of chromatography A, vol. 858, no. 1, pp. 13-31, October 1999.
[22] L. F. Lira, D. C. Dos Santos, M. A. Guida, L. Stragevitch, A. K. Maria das Graças, M. F. Pimentel, and A. P. Paim, “Determination of phosphorus in biodiesel using FIA with spectrophotometric detection”, Fuel, vol. 90, no. 11, pp. 3254-3258, November 2011.
[23] E. J. Mercer, and F. Halaweish, “Determination of free glycerol in biodiesel via solid-phase extraction and spectrophotometric analysis”, Journal of the American Oil Chemists’ Society, vol. 88, no. 5, pp. 655-659, May 2011.
[24] T. A. Chimenez, K. F. Magalhães, A. R. Caires, and S. L. Oliveira, “Fluorescence as an analytical tool for assessing the conversion of oil into biodiesel”, Journal of fluorescence, vol. 22, no. 4, pp. 1177-1182, July 2012.
[25] M. Meira, C. M. Quintella, A. dos Santos Tanajura, H. R. Da Silva, J. D. Fernando, P. R. da Costa Neto, I. M. Pepe, M. A. Santos, and L. L. Nascimento, “Determination of the oxidation stability of biodiesel and oils by spectrofluorimetry and multivariate calibration”, Talanta, vol. 85, no. 1, pp. 430-434, July 2011.
[26] M. Meira, C. M. Quintella, T. M. Ferrer, H. R. Silva, A. K. Guimarães, M. A. Santos, P. R. Costa Neto, I. M. Pepe, “Identification of adulteration of biofuel by addition of residual oil instead of biodiesel to the diesel by total spectrofluorimetry and principal component analysis”, Química Nova, vol. 34, no. 4, pp. 621-624, June 2011.
[27] N. Dupuy, Y. Le Dréau, D. Ollivier, J. Artaud, C. Pinatel, and J. Kister, “Origin of French virgin olive oil registered designation of origins predicted by chemometric analysis of synchronous excitation− emission fluorescence spectra”, Journal of agricultural and food chemistry, vol. 53, no. 24, pp. 9361-9368, November 2005.
[28] E. Sikorska, T. Górecki, Khmelinskii IV, M. Sikorski, and J. Kozioł, “Classification of edible oils using synchronous scanning fluorescence spectroscopy”, Food Chemistry, vol. 89, no. 2, pp. 217-225, February 2005.
[29] E. Sikorska, A. Romaniuk, Khmelinskii I, M. Sikorski, and J. Kozioł, “Characterization of edible oils using synchronous scanning fluorescence spectroscopy”, Polish journal of food and nutrition sciences, vol. 2, no. 2, pp. 108-112, June 2003.
[30] K. I. Poulli, N. V. Chantzos, G. A. Mousdis, and C. A. Georgiou, “Synchronous fluorescence spectroscopy: tool for monitoring thermally stressed edible oils”, Journal of agricultural and food chemistry. vol. 57, no. 18, pp. 8194-8201, September 2009.
[31] R. J. Hurtubise, “Selective fluorescence quenching and determination of phenolic antioxidants”, Analytical Chemistry, vol. 48, no. 14, pp. 2092-2094, December 1976.
[32] M. Zandomeneghi, L. Carbonaro, and C. Caffarata, “Fluorescence of vegetable oils: olive oils”, Journal of agricultural and food chemistry, vol. 53, no. 3, pp. 759-766, February 2005.
[33] M. E. Escuderos, A. Sayago, M. T. Morales, and R. Aparicio, “Evaluation of α-tocopherol in virgin olive oil by a luminescent method”, Grasas y aceites, vol. 60, no. 4, pp. 336-342, September 2009.
[34] E. Sikorska, A. Romaniuk, Khmelinskii IV, R. Herance, J. L. Bourdelande, M. Sikorski, and J. Kozioł, “Characterization of edible oils using total luminescence spectroscopy”, Journal of Fluorescence, vol. 14, no. 1, pp. 25-35, January 2004.
[35] E. Sikorska, A. Gliszczyńska-Świgło, Khmelinskii I, and M. Sikorski, “Synchronous fluorescence spectroscopy of edible vegetable oils. Quantification of tocopherols”, Journal of agricultural and food chemistry, vol. 53, no. 18, pp. 6988-6994, September 2005.
[36] T. Izida, L. Bussler, J. R. Silva, L. H. Andrade, E. Simionatto, E. L. Simionatto, D. R. Scharf, and S. M. Lima, “On-line in situ monitoring of the soybean oil and ethanol transesterification reaction by fluorescence spectroscopy”, Fuel, vol. 145, pp. 109-115, April 2015.
[37] M. I. Arbab, H. H. Masjuki, M. Varman, M. A. Kalam, S. Imtenan, and H. Sajjad, “Fuel properties, engine performance and emission characteristic of common biodiesels as a renewable and sustainable source of fuel”, Renewable and Sustainable Energy Reviews, vol. 22, pp. 133-147, June 2013.
[38] D. Darnoko, and M. Cheryan, “Kinetics of palm oil trans-esterification in a batch reactor”, Journal of American Oil Chemical Society, vol. 77, no. 12, pp. 1263-1267, June 2000.
[39] M. Han, K. Cho, C. S. Sluder, and R. M. Wagner, “Soybean and coconut biodiesel fuel effects on combustion characteristics in a light-duty diesel engine”, SAE Technical Paper, October 2008.
[40] D. Qi, M. Leick, Y. Liu, and F. L. Chia-fon, “Effect of EGR and injection timing on combustion and emission characteristics of split injection strategy DI-diesel engine fueled with biodiesel”, Fuel, vol. 90, no. 5, pp. 1884-1891, May 2011.
[41] P. R. Wander, C. R. Altafini, A. L. Colombo, and S. C. Perera, “Performance of small stationary engines using blends of diesel fuel with biodiesel of soybean”, SAE Technical Paper, October 2010.
[42] X. Zhang, G. Gao, L. Li, Z. Wu, Z. Hu, and J. Deng, “Characteristics of combustion and emissions in a DI engine fueled with biodiesel blends from soybean oil”, SAE Technical Paper, June 2008.
[43] O. S. Valente, M. J. Da Silva, V. M. Pasa, C. R. Belchior, and J. R. Sodré, “Fuel consumption and emissions from a diesel power generator fuelled with castor oil and soybean biodiesel”, Fuel, vol. 89, no. 12. pp. 3637-3642, December 2010.
[44] D. H. Qi, L. M. Geng, H. Chen, Y. Z. Bian, J. Liu, and X. C. Ren, “Combustion and performance evaluation of a diesel engine fueled with biodiesel produced from soybean crude oil”, Renewable Energy, vol. 34, no. 12, pp. 2706-2713, December 2009.
[45] A. V. Bueno, J. A. Velásquez, and L. F. Milanez, “Heat release and engine performance effects of soybean oil ethyl ester blending into diesel fuel”, Energy, vol. 36, no. 6, pp. 3907-3916, June 2011.
[46] I. Celıkten, “An experimental investigation of the effect of the injection pressure on engine performance and exhaust emission in indirect injection diesel engines”, Applied Thermal Engineering, vol. 23, no. 16, pp. 2051-2060, November 2003.
[47] B. Gokalp, E. Buyukkaya, and H. S. Soyhan, “Performance and emissions of a diesel tractor engine fueled with marine diesel and soybean methyl ester”, Biomass and bioenergy, vol. 35, no. 8, pp. 3575-3583, August 2011.
[48] Taxonomy for Plants, “National Genetic Resources Program”, National Germplasm Resources Laboratory, Beltsville, Maryland, USDA, 2014.
[49] F. Yasar, S. Altun, and H. Adin, “Fuel properties of biodiesels produced from blends of canola oil and animal tallow”, Energy Educ Sci Technol Part A, vol. 27, pp. 199-208, April 2011.
[50] W. Gis, A. Żółtowski, and A. Bocheńska, “Properties of the rapeseed oil methyl esters and comparing them with the diesel oil properties”, Journal of KONES, vol. 18, pp. 121-127, June 2011.
[51] S. P. Singh, and D. Singh, “Biodiesel production through the use of different sources and characterization of oils and their esters as the substitute of diesel: a review”, Renewable and sustainable energy reviews, vol. 14, no. 1, pp. 200-216, January 2010.
[52] M. Zheng, M. C. Mulenga, G. T. Reader, M. Wang, D. S. Ting, and J. Tjong, “Biodiesel engine performance and emissions in low temperature combustion”, Fuel, vol. 87, no. 6, pp. 714-722, May 2008.
[53] T. C. Zannis, D. T. Hountalas, and D. A. Kouremenos, “Experimental investigation to specify the effect of oxygenated additive content and type on DI diesel engine performance and emissions”, SAE Technical Paper, March 2004.
[54] I. Celıkten, “An experimental investigation of the effect of the injection pressure on engine performance and exhaust emission in indirect injection diesel engines”, Applied Thermal Engineering, vol. 23, no. 16, pp. 2051-2060, November 2003.
[55] A. Tsolakis, A. Megaritis, M. L. Wyszynski, and K. Theinnoi, “Engine performance and emissions of a diesel engine operating on diesel-RME (rapeseed methyl ester) blends with EGR (exhaust gas recirculation)”, Energy, vol. 32, no. 11, pp. 2072-2080, November 2007.
[56] E. Kinoshita, K. Hamasaki, and C. Jaquin, “Diesel Combustion of Palm Oil Mehtyl Ester”, SAE Technical Paper No. 2003-01-1929, 2003.
[57] G. Labeckas, and S. Slavinskas, “The effect of rapeseed oil methyl ester on direct injection diesel engine performance and exhaust emissions”, Energy conversion and Management, vol. 47, no. 13, pp. 1954-1967, August 2006.
[58] A. Kumar, and S. Sharma, “An evaluation of multipurpose oil seed crop for industrial uses (Jatropha curcas L.): a review”, Industrial crops and products, vol. 28, no. 1, pp. 1-10, July 2008.
[59] K. Openshaw, “A review of Jatropha curcas: an oil plant of unfulfilled promise”, Biomass and bioenergy, vol. 19, no. 1, pp. 1-5, July 2000.
[60] W. M. Achten, L. Verchot, Y. J. Franken, E. Mathijs, V. P. Singh, R. Aerts, B. Muys, “Jatropha bio-diesel production and use”, Biomass and bioenergy, vol. 32, no. 12, pp. 1063-1084, December 2008.
[61] R. K. Singh, and S. K. Padhi, “Characterization of jatropha oil for the preparation of biodiesel, 2009.
[62] W. Parawira, “Biodiesel production from Jatropha curcas: A review”, Scientific Research and Essays, vol. 5, no. 14, pp. 1796-1808, July 2010.
[63] S. Choudhury, and P. K. Bose, “Jatropha derived biodiesel–its suitability as CI engine fuel”, SAE Technical Paper, January 2008.
[64] I. K. Reksowardojo, I. H. Lubis, W. Manggaia, T. P. Brodjonegoro, T. H. Soerawidjaja, and W. Arismunandar, “Performance and Exhaust Gas Emissions of Using Biodiesel fuel from Jatropha”, SAE Technical Paper No. 2007-01-2025, 2007.
[65] B. S. Chauhan, N. Kumar, and H. M. Cho, “A study on the performance and emission of a diesel engine fueled with Jatropha biodiesel oil and its blends”, Energy, vol. 37, no. 1, pp. 616-622, January 2012.
[66] T. Ganapathy, R. P. Gakkhar, and K. Murugesan, “Influence of injection timing on performance, combustion and emission characteristics of Jatropha biodiesel engine”, Applied energy, vol. 88, no. 12, pp. 4376-4386, December 2011.
[67] M. J. Abedin, H. H. Masjuki, M. A. Kalam, A. Sanjid, S. A. Rahman, and I. R. Fattah, “Performance, emissions, and heat losses of palm and jatropha biodiesel blends in a diesel engine”, Industrial crops and products, vol. 59, pp. 96-104, August 2014.
[68] J. Huang, Y. Wang, J. B. Qin, and A. P. Roskilly, “Comparative study of performance and emissions of a diesel engine using Chinese pistache and jatropha biodiesel”, Fuel Processing Technology, vol. 91, no. 11, pp. 1761-1767, November 2010.
[69] M. A. Fazal, A. S. Haseeb, and H. H. Masjuki, “Biodiesel feasibility study: an evaluation of material compatibility; performance; emission and engine durability”, Renewable and Sustainable Energy Reviews, vol. 15, no. 2, pp. 1314-1324, February 2011.
[70] E. C. Abbah, G. I. Nwandikom, C. C. Egwuonwu, and N. R. Nwakuba, “Effect of Reaction Temperature on the Yield of Biodiesel From Neem Seed Oil”, American Journal of Energy Science, vol. 3, no. 3, pp. 16-20, June 2016.
[71] K. D. Kumar, and P. R. Kumar, “Experimental investigation of cotton seed oil and neem methyl esters as biodiesel on CI engine”, International Journal of Modern Engineering Research, vol. 2, no. 4, pp. 1741-1746, July 2012.
[72] P. T. Porai, and N. Nagarajan, “Evaluation of performance & emission of neem oil methyl ester in a DI diesel engine”, Asian Journal of Computer Science & Information Technology, vol. 3, no. 4, October 2013.
[73] L. Prabhu, S. S. Kumar, M. Prabhahar, and K. Rajan, “Combustion, performance and emission characteristics of diesel engine with neem oil methyl ester and its diesel blends”, American Journal of Applied Sciences, vol. 10, no. 8, pp. 810-818, June 2013.
[74] S. Sivalakshmi, and T. Balusamyb, “Experimental investigation on a diesel engine using neem oil and its methyl ester”, Thermal science, vol. 15, no. 4, pp. 1193-1204, June 2011.
[75] N. P. Oza, P. P. Rathod, and N. K. Patel, “Performance Comparison of 4-stroke Multi–Cylinder CI Engine Using Neem Biodiesel and Diesel as Fuel”, In Proceedings of The Indian Journal of Technical Education 1st National Conference of Futuristic Trends in Mechanical Engineering, 2012, pp. 143-148.
[76] K. Sivaramakrishnan, and P. Ravikumar, “Performance optimization of karanja biodiesel engine using taguchi approach and multiple regressions”, ARPN J. of Engineering and Applied Sciences, vol. 7, pp. 507-516, June 2012.
[77] M. V. Nagarhalli, V. M. Nandedkar, and K. C. Mohite, “Emission and performance characteristics of karanja biodiesel and its blends in a CI engine and it’s economics”, ARPN Journal of Engineering and Applied Sciences, vol. 5, no. 2, pp. 52-56, February 2010.
[78] A. K. Pandey, and M. R. Nandgaonkar, “Experimental investigation of the effect of Esterified Karanja oil biodiesel on performance, emission and engine wear of a military 160hp Turbocharged CIDI engine”, In Proceedings of the world congress on engineering, 2011, vol. 3, pp. 6-8.
P. K. Sahoo, L. M. Das, M. K. Babu, P. Arora, V. P. Singh, N. R. Kumar, and T. S. Varyani, “Comparative evaluation of performance and emission characteristics of jatropha, karanja and polanga based biodiesel as fuel in a tractor engine”, Fuel, vol. 88, no. 9, pp. 1698-1707, September 2009.